Electroreduction of neodymium and praseodymium ions in equimolar KCl-NaCl and eutectic KCl-NaCl-CsCl melts at a tungsten electrode

被引：2
|
作者：
Kushkhov K.B. [1 ]
Chuksin S.I. [1 ]
Zhanikaeva Z.A. [1 ]
机构：
[1] Kabardino-Balkarian State University, Nal'chik
来源：
Russian Metallurgy (Metally) | 2013年 / 2013卷 / 8期
关键词：
Neodymium; CsCl; RUSSIAN Metallurgy; Praseodymium; Electrode Process;
D O I：
10.1134/S0036029513080077
中图分类号：
学科分类号：
摘要：
Cyclic voltammetry is used to study the processes that occur during the electroreduction of neodymium and praseodymium ions in equimolar KCl-NaCl (at 973 K) and eutectic KCl-NaCl-CsCl (at 823 K) melts at a tungsten electrode. The kinetics parameters and the diffusion coefficients of neodymium and praseodymium ions are calculated. © 2013 Pleiades Publishing, Ltd.
引用
收藏
页码：610 / 616
页数：6
相关论文
共 50 条
  • [1] STRUCTURE AND ACTION OF AG/AGCL,KCL-NACL/SUPREMAX REFERENCE ELECTRODE IN EQUIMOLAR KCL-NACL MELTS
    EICHLER, B
    ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-LEIPZIG, 1972, 249 (3-4): : 195 - &
  • [2] Electrochemical Behavior of Neodymium Ions and Their Combined Electroreduction with Nickel Ions in the KCl–NaCl–CsCl Eutectic Melt
    Kushkhov K.B.
    Kholkina A.S.
    Ali Z.Z.
    Khotov A.A.
    Pashtova L.R.
    Russian Metallurgy (Metally), 2023, 2023 (08) : 1175 - 1192
  • [3] Cooperative Electroreduction of Cerium and Nickel Ions in the Equimolar KCl-NaCl Melt at 973 K
    Kushkhov, Kh. B.
    Kisheva, F. A.
    Vindizheva, M. K.
    Mukozheva, R. A.
    RUSSIAN METALLURGY, 2024, 2024 (04): : 954 - 959
  • [4] Electrochemical Behavior of Dysprosium Ion and Its Co-Electroreduction with Nickel Ions in the Molten KCl-NaCl-CsCl Eutectic
    Khushkhov, Khasbi B.
    Kholkina, Anna S.
    Khotov, Astemir A.
    Ali, Zhubagi Z.
    Zhanikayeva, Zalina A.
    Kvashin, Vadim A.
    Kovrov, Vadim A.
    Mushnikova, Anastasia A.
    Mirzayants, Daria P.
    PROCESSES, 2023, 11 (10)
  • [5] STUDIES ON THE ELECTROREDUCTION OF URANYL (VI) IN MOLTEN EQUIMOLAR KCL-NACL BY CHRONOPOTENTIOMETRIC AND ELECTRODE IMPEDANCE MEASUREMENTS
    STROMATT, RW
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1963, 110 (12) : 1277 - 1282
  • [6] PRODUCTION OF TUNGSTEN COATINGS BY ELECTROLYSIS OF OXYCHLORIDE MELTS BASED ON AN EQUIMOLAR KCl-NaCl MIXTURE.
    Delimarskii, Yu.K.
    Parkhomenko, N.I.
    Grishchenko, V.F.
    Protection of Metals, 1976, 12 (06): : 633 - 634
  • [7] Electroreduction of yttrium ions in an equimolar NaCl–KCl molten mixture
    Tolstobrov I.V.
    El’kin O.V.
    Kovalevskii A.V.
    Chebykin V.V.
    Russ. Metall. (Metally), 8 (626-630): : 626 - 630
  • [8] A study of samarium ions electroreduction at various electrodes in KCl-NaCl-CsCl melt at T = 823 K
    Kh. B. Kushkhov
    M. K. Vindizheva
    R. A. Karashaeva
    M. R. Tlenkopachev
    Russian Journal of Electrochemistry, 2010, 46 : 691 - 701
  • [9] A study of samarium ions electroreduction at various electrodes in KCl-NaCl-CsCl melt at T=823 K
    Kushkhov, Kh B.
    Vindizheva, M. K.
    Karashaeva, R. A.
    Tlenkopachev, M. R.
    RUSSIAN JOURNAL OF ELECTROCHEMISTRY, 2010, 46 (06) : 691 - 701
  • [10] Mechanism of the Combined Electroreduction of Dy3+ and Fe3+ Ions in the KCl-NaCl-CsCl Eutectic Melt at 823 K
    Kushkhov, Kh. B.
    Khotov, A. A.
    Kholkina, A. S.
    Khasanov, V. V.
    Dudarova, D. G.
    RUSSIAN METALLURGY, 2024, 2024 (01): : 239 - 246
12345