Thermo-responsive Ruthenium Dendrimer-based Catalysts for Hydrogenation of the Aromatic Compounds and Phenols

被引：0
|
作者：
E. Karakhanov
A. Maximov
A. Zolotukhina
Yu. Kardasheva
M. Talanova
机构：
[1] Moscow State University,Department of Petroleum Chemistry and Organic Catalysis
[2] A. V. Topchiev Institute of Petrochemical Synthesis RAS,undefined
来源：
Journal of Inorganic and Organometallic Polymers and Materials | 2016年 / 26卷
关键词：
Ruthenium nanoparticles; Hydrogenation; Dendrimers; PEG; Thermo-responsive catalysts;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
In this work thermo-responsive ruthenium catalysts, based on the poly(propylene imine) dendrimers cross-linked with the poly(ethylene glycol) diglycidyl ether, have been prepared for the first time. The materials obtained were characterized by X-ray photoelectron spectroscopy and transmission electron microscopy, and tested in the phenol and benzene hydrogenation. Conditions for the metal impregnation into the polymeric matrix were demonstrated to have a great influence both on physical chemical properties of the synthesized catalysts (metal loading, mean particles size, surface structure etc.), and, as a consequence, on their hydrogenation activity and thermo-responsive properties.
引用
收藏
页码：1264 / 1279
页数：15
相关论文
共 50 条
  • [1] Thermo-responsive Ruthenium Dendrimer-based Catalysts for Hydrogenation of the Aromatic Compounds and Phenols
    Karakhanov, E.
    Maximov, A.
    Zolotukhina, A.
    Kardasheva, Yu.
    Talanova, M.
    JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2016, 26 (06) : 1264 - 1279
  • [2] Nanostructured Ruthenium Catalysts in Hydrogenation of Aromatic Compounds
    Glotov, A. P.
    Stavitskaya, A. V.
    Chudakov, Ya. A.
    Artemova, M. I.
    Smirnova, E. M.
    Demikhova, N. R.
    Shabalina, T. N.
    Gureev, A. A.
    Vinokurov, V. A.
    PETROLEUM CHEMISTRY, 2018, 58 (14) : 1221 - 1226
  • [3] Nanostructured Ruthenium Catalysts in Hydrogenation of Aromatic Compounds
    A. P. Glotov
    A. V. Stavitskaya
    Ya. A. Chudakov
    M. I. Artemova
    E. M. Smirnova
    N. R. Demikhova
    T. N. Shabalina
    A. A. Gureev
    V. A. Vinokurov
    Petroleum Chemistry, 2018, 58 : 1221 - 1226
  • [4] Interaction of phenols with thermo-responsive hydrogels
    Kosik, Katalin
    Wilk, Erzsebet
    Geissler, Erik
    Laszlo, Krisztina
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2008, 319 (1-3) : 159 - 164
  • [5] Heterogeneous Dendrimer-Based Catalysts
    Karakhanov, Eduard
    Maximov, Anton
    Zolotukhina, Anna
    POLYMERS, 2022, 14 (05)
  • [6] Dendrimer-based nanocomposites as catalysts.
    Balogh, L
    Brubaker, J
    Chamberlain, T
    Tomalia, DA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 216 : U638 - U638
  • [7] Design of dendrimer-based nanostructured catalyst systems and their catalytic activity in hydrogenation: Synthesis of ruthenium nanoparticles immobilized in dendrimer networks
    Karakhanov, E. A.
    Maksimov, A. L.
    Zolotukhina, A. V.
    Kardashev, S. V.
    PETROLEUM CHEMISTRY, 2010, 50 (04) : 290 - 297
  • [8] Design of dendrimer-based nanostructured catalyst systems and their catalytic activity in hydrogenation: Synthesis of ruthenium nanoparticles immobilized in dendrimer networks
    E. A. Karakhanov
    A. L. Maksimov
    A. V. Zolotukhina
    S. V. Kardashev
    Petroleum Chemistry, 2010, 50 : 290 - 297
  • [9] Ruthenium catalysts based on mesoporous aromatic frameworks for the hydrogenation of arenes
    Maximov, Anton
    Zolotukhina, Anna
    Kulikov, Leonid
    Kardasheva, Yulia
    Karakhanov, Eduard
    REACTION KINETICS MECHANISMS AND CATALYSIS, 2016, 117 (02) : 729 - 743
  • [10] Ruthenium catalysts based on mesoporous aromatic frameworks for the hydrogenation of arenes
    Anton Maximov
    Anna Zolotukhina
    Leonid Kulikov
    Yulia Kardasheva
    Eduard Karakhanov
    Reaction Kinetics, Mechanisms and Catalysis, 2016, 117 : 729 - 743
12345