The influence of solvent structure on the solvolysis of a ruthenium(II) complex in water–acetonitrile mixtures

被引：0
|
作者：
Mohamed Khalifa
Mervette El-Batouti
Ateyat El-Hawaty
机构：
[1] Alexandria University,Department of Chemistry, Faculty of Science
来源：
Transition Metal Chemistry | 2003年 / 28卷
关键词：
Spectroscopy; Physical Chemistry; Inorganic Chemistry; Acetonitrile; Catalysis;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The solvent effect on the rate of aquation of trans-[Ru(py)4Cl2] has been investigated by u.v. spectroscopy in the 40–55 °C range in MeCN–H2O media. The thermodynamic activation parameters are calculated and discussed in terms of solvation effects. Log k was correlated with the reciprocal of the dielectric constant. A non-linear correlation was obtained and is discussed on the basis of specific solvation.
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页码：489 / 493
页数：4
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