Transition metal-catalyzed decarboxylative cross-coupling reactions

被引：0

作者：

Rui Shang

Lei Liu

机构：

[1] Tsinghua University,Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education); Department of Chemistry

[2] Chinese Academy of Sciences,State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry

来源：

Science China Chemistry | 2011年 / 54卷

关键词：

decarboxylation; cross-coupling reaction; transition metal; catalysis; organic synthesis;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Transition metal-catalyzed decarboxylative cross-coupling reactions have recently emerged as a new and important category of organic transformations that find versatile applications in the construction of carbon-carbon and carbon-heteroatom bonds. The use of relatively cheap and stable carboxylic acids to replace organometallic reagents enables the decarboxylative cross-coupling reactions to proceed with good selectivities and functional group tolerance. In the present review we summarize the various types of decarboxylative cross-coupling reactions catalyzed by different transition metal complexes. The scope and applications of these reactions are described. The challenges and opportunities in the field are discussed.

引用

页码：1670 / 1687

页数：17

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