Crystal structure of Cs8[α-BW12O40][RhCl6]·5·5H2O double salt

被引：0
|
作者：
M. N. Sokolov
V. S. Korenev
E. V. Peresypkina
V. P. Fedin
机构：
[1] Russian Academy of Sciences,A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division
[2] Novosibirsk State University,undefined
来源：
Journal of Structural Chemistry | 2010年 / 51卷
关键词：
heteropolytungstates; boron; rhodium; double salts; crystal structure;
D O I：
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中图分类号：
学科分类号：
摘要：
By heating in the air [HBW11O39]8− with [Rh2(CH3COO)4(H2O)2] in the excess of tungstate followed by crystallization in the presence of CsCl, a double salt of Cs8[6h-BW12O40][RhCl6]·5.5H2O is obtained and structurally characterized. Its crystal structure is determined by single crystal X-ray diffraction. The structure is ionic with Cs+ cations, [BW12O40]5 anions with the Keggin structure, and [RhCl6]3 octahedral anions.
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页码：984 / 986
页数：2
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