Inhibition effect of a new pyrimidine derivative on the corrosion of mild steel in hydrochloric acid solution

被引:11
|
作者
Shetty P.B. [1 ]
Suresha Kumara T.H. [2 ]
Mamatha D.M. [2 ]
Rao V.R. [3 ]
Chitharanjan Hegde A. [3 ]
机构
[1] Department of Chemistry, Jain University, Hebbal, Bangalore
[2] Department of Chemistry, U.B.D.T. College of Engineering, (A Constituent College of Visweswaraya Technological University), Davanagere
[3] Electrochemistry Research Laboratory, Department of Chemistry, National Institute of Technology, Surathkal Srinivasnagar, 575025, Karnataka
来源
Suresha Kumara, T.H. (suresha.kumara@gmail.com) | 1600年 / Allerton Press Incorporation卷 / 53期
关键词
electrochemical impedance spectroscopy; mild steel; scanning electron microscopy; Tafel extrapolation technique;
D O I
10.3103/S1068375517010112
中图分类号
学科分类号
摘要
The inhibition effect of a newly synthesized pyrimidine derivative, namely 3-(2-(4-(hydroxymethyl)-1H-1,2,3-triazol-1-yl)ethyl)-2-methyl-6,7,8,9-tetrahydropyrido[1,2-a]pyrimidin-4-one, on the corrosion of mild steel in 1.0 M HCl medium was investigated using the weight loss, the Tafel extrapolation technique and the AC impedance spectroscopy. The effect of the inhibitor concentration, temperature and concentration of the acid mixture media on the inhibitor action was also studied. It was observed that the anti-corrosion efficiency increases with an increase in the inhibitor concentration, but decreases with an increase in temperature. Thermodynamic parameters for the dissolution process were determined. The adsorption of the pyrimidine derivative on the mild steel surface was found to obey the Langmuir adsorption isotherm. © 2017, Allerton Press, Inc.
引用
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页码:42 / 51
页数:9
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