Magnetism and Photocatalytic Degradation of Organic Dyes Based on a New Metal Formate Framework

被引：0

作者：

F. M. Wang

B. H. Li

Z. D. Luo

J. Q. Liu

H. Sakiyama

A. Q. Ma

机构：

[1] Shaanxi Xueqian Normal University,Department of Chemistry and Chemical Engineering

[2] Guangdong Medical University,Key Laboratory for Research and Development of New Medical Materials of Guangdong Medical University, Dongguan Key Laboratory of Drug Design and Formulation Technology, School of Pharmacy

[3] Yamagata University,Department of Material and Biological Chemistry, Faculty of Science

来源：

Russian Journal of Coordination Chemistry | 2018年 / 44卷

关键词：

magnetism; formate; photocatalytic property;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

A new MOF of [Co(HCOO)2] · 0.33DMF (I) was prepared and characterized by IR, powder X-ray diffraction, and single-crystal X-ray diffraction (CIF file CCDC no. 1571166). Complex I exhibits a diamond framework based on Co-centered CoCo4 tetrahedral nodes, in which all metal ions have octahedral coordination geometry and all HCOO groups link the metal ions in syn-syn/anti modes. The magnetic property shows a main antiferromagnetic interaction and the ferromagnetic phase transition below 2 K. Furthermore, the photocatalytic properties of I for degradation of the methyl violet and Rhodamine B have been explored.

引用

页码：415 / 420

页数：5

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