Functionalized Polyphosphoester via Living Ring-opening Polymerization and Photochemical Thiol-ene Click Reaction

被引：0
|
作者：
Ying Wang
Qiliao Wang
Liman Hou
Mingdong Zhou
Dewen Dong
Ning Zhang
机构：
[1] Liaoning Shihua University,School of Chemistry and Materials Science
[2] Chinese Academy of Sciences,CAS Key Laboratory of High
[3] University of Science and Technology of China,performance Synthetic Rubber and Its Composite Materials, Changchun Institute of Applied Chemistry
来源：
Chemical Research in Chinese Universities | 2019年 / 35卷
关键词：
Cyclic phosphonate; Ring-opening polymerization; Thiol-ene click reaction; Post modification;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Poly(ethylene phosphonate) was synthesized via the living ring-opening polymerization of cyclic phosphonate monomer catalyzed by organocatalyst. The pendant vinyl functionalities were employed to perform the photochemical click reactions with thiols. We demonstrated that both small thiol molecules and macromolecular thiols could be efficiently coupled into the PPE side chains, enabling the rapid and efficient functionalization of polyphosphoesters( PPE).
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页码：340 / 344
页数：4
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