Synthesis and structure of triphenylbismuth bis(pentachlorobenzoate)

被引：0
|
作者：
V. V. Sharutin
O. K. Sharutina
机构：
[1] National South Ural State Research University,
来源：
Russian Journal of Inorganic Chemistry | 2014年 / 59卷
关键词：
Dicarboxylates; Bipyramidal; Carboxylate Ligand; Bismuth Atom; Trigonal Bipyramidal Coordination;
D O I：
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学科分类号：
摘要：
Triphenylbismuth bis(pentachlorobenzoate) has been synthesized by the reaction between triphenylbismuth and pentachlorobenzoic acid in the presence of hydrogen peroxide in ether. According to X-ray diffraction data, the bismuth atoms in two crystallographically independent molecules (A and B) have a distorted trigonal bipyramidal coordination. The OBiO and CBiC angles between axial and equatorial substituents are 171.7(3)°, 173.6(3)°, and 105.3(4)°–146.9(4)°. The Bi-O and Bi-C bond lengths are 2.291(8)–2.315(8) and 2.197(11)–2.204(10) Å, respectively. The Bi…O(=C) distances are 2.843(10)–2.857(11) Å.
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页码：558 / 560
页数：2
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