Reaction of O,O-dialkyldithiophosphoric acid with N-tert-butyl-2,2-dihalopropanimines

被引：0
|
作者：
M. B. Gazizov
R. A. Khairullin
N. G. Aksenov
Yu. S. Kirillina
A. Yu. Bandikova
机构：
[1] Kazan National Research Technological University,
来源：
Russian Chemical Bulletin | 2016年 / 65卷
关键词：
dialkyldithiophosphoric acids; dichloropropanimine; dibromopropanimine; iminium salt; reduction of carbon—halogen bond; nucleophilic substitution of halogen; bis(dialkoxythiophosphoryl) disulfide;
D O I：
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摘要：
O,O-Dialkyldithiophosphoric acid reacted with N-tert-butyl-2,2-dihalopropanimines to give iminium salt as a primary product, which further sequentially undergoes reaction with two equivalents of dithiophosphoric acid to initially reduce the C—X (X = Cl, Br) bond in the iminium salt and then nucleophilic replacement of the halogen atom with dialkoxydithiophosphate group. The final reaction products are the reduction—substitution product of the primary salt and bis(dialkoxythiophosphoryl) disulfide.
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页码：1119 / 1121
页数：2
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