Clean Baeyer–Villiger Oxidation Using Hydrogen Peroxide as Oxidant Catalyzed by Aluminium Trichloride in Ethanol

被引：3
|
作者：
Ziqiang Lei
Guofu Ma
Linlin Wei
Quanlu Yang
Bitao Su
机构：
[1] Northwest Normal University,Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering
来源：
Catalysis Letters | 2008年 / 124卷
关键词：
Baeyer–Villiger oxidation; Ketones; Aluminium trichloride; Ethanol;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Baeyer–Villiger oxidation of ketones was carried out using AlCl3 as catalyst, H2O2 (30%) as oxidant in innocuity and environmentally friendly ethanol conditions. Cyclic ketones and acyclic ketones were transformed into the corresponding lactones or esters in 5–24 h at 40–70 °C with very high conversion and selectivity. A possible reaction mechanism was also given.
引用
收藏
页码：330 / 333
页数：3
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