Mathematical modeling of toluene oxidation with a periodic reactor operation

被引：0
|
作者：
S. I. Reshetnikov
机构：
[1] Boreskov Institute of Catalysis,
来源：
Reaction Kinetics, Mechanisms and Catalysis | 2010年 / 99卷
关键词：
Vanadia/titania catalyst; Toluene partial oxidation; Nonsteady-state kinetic model; Mathematic modeling;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Mathematical modeling of toluene oxidation under unsteady state catalyst created by forced oscillations of concentration of toluene in the reactor inlet was carried out. It is shown that, under periodic reactor operation, the benzaldehyde yield was up to several times higher than the steady state value. This was explained by the participation of different oxygen species in the partial and total oxidation on the catalyst surface.
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页码：23 / 28
页数：5
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