Styrene oligomerization in the presence of catalytic systems based on Pd(acac)2 and BF3OEt2

被引：0
|
作者：
V. S. Tkach
G. Myagmarsuren
M. Mesyef
F. K. Shmidt
机构：
[1] Irkutsk State University,
来源：
Reaction Kinetics and Catalysis Letters | 1999年 / 66卷
关键词：
Palladium; styrene; oligomerization;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Styrene oligomerization in the presence of Pd(acac)2+PPh3+BF3OEt2 catalytic system (acac—acetylacetonate) has been studied. Styrene conversion at optimum conditons (T=343 K, B/Pd=7, P/Pd=2) was as high as 75,000 mol of C3H3 per mol of Pd in 7 h with a selectivity to dimers, mostly 1,3-diphenylbut-1-ene, up to 93%.
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页码：281 / 287
页数：6
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