Sol–Gel Synthesis and Textural–Structural Characteristics of Manganese Oxide: the Effect of Thermal-Modification Temperature

被引：0
|
作者：
Saenko E.V. [1 ]
机构：
[1] Perm Federal Research Center, Ural Branch, Russian Academy of Sciences, Perm
来源：
Polymer Science - Series D | 2023年 / 16卷 / 03期
基金：
俄罗斯基础研究基金会;
关键词：
birnessite; H-form; low-temperature nitrogen adsorption; manganese oxide; specific surface area; textural properties; thermal modification temperature;
D O I：
10.1134/S1995421223030279
中图分类号：
学科分类号：
摘要：
Abstract: Using the sol–gel method, by reacting solutions of maleic acid and potassium permanganate, samples have been obtained with a turbostat stacking of layers, which is characteristic of the birnessite structure. Using X-ray phase and thermogravimetric analysis, Raman spectroscopy, and low-temperature nitrogen adsorption, the dependence of the textural–structural characteristics of the synthesized materials on the temperature of thermal modification (150, 360°C) and sample composition (Sr-form, H-form) has been shown. It has been found that all samples are characterized by a mesoporous texture. It is shown that the water content in the samples is closely related to the quantitative determination of the specific surface area: the more water, the greater the S BET value. © 2023, Pleiades Publishing, Ltd.
引用
收藏
页码：518 / 521
页数：3
相关论文
共 50 条
  • [1] ON THE EFFECTS OF THE SOL-GEL SYNTHESIS PARAMETERS ON TEXTURAL AND STRUCTURAL CHARACTERISTICS OF TIO2
    MONTOYA, IA
    VIVEROS, T
    DOMINGUEZ, JM
    CANALES, LA
    SCHIFTER, I
    CATALYSIS LETTERS, 1992, 15 (1-2) : 207 - 217
  • [2] Sol-gel synthesis and characterization of mesoporous manganese oxide
    Hong, XL
    Zhang, GY
    Zhu, YY
    Yang, HQ
    MATERIALS RESEARCH BULLETIN, 2003, 38 (13) : 1695 - 1703
  • [3] STRUCTURAL AND ELECTROCHEMICAL CHARACTERISTICS OF A LAMELLAR SODIUM MANGANESE OXIDE SYNTHESIZED VIA A SOL-GEL PROCESS
    LEGOFF, P
    BAFFIER, N
    BACH, S
    PEREIRARAMOS, JP
    MESSINA, R
    SOLID STATE IONICS, 1993, 61 (04) : 309 - 315
  • [4] Sol-gel synthesis and adsorption properties of mesoporous manganese oxide
    Ivanets, A. I.
    Kuznetsova, T. F.
    Prozorovich, V. G.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2015, 89 (03) : 481 - 486
  • [5] Sol-gel synthesis and adsorption properties of mesoporous manganese oxide
    A. I. Ivanets
    T. F. Kuznetsova
    V. G. Prozorovich
    Russian Journal of Physical Chemistry A, 2015, 89 : 481 - 486
  • [6] Humidity sensing characteristics of manganese oxide prepared by sol-gel method
    Kato, T
    Tanaka, Y
    Hirata, T
    Kumamoto, S
    Miyazaki, K
    JOURNAL OF MATERIALS SCIENCE LETTERS, 1997, 16 (21) : 1771 - 1773
  • [7] Sol-gel synthesis of manganese oxide films and their predominant electrochemical properties
    Sarkar, Abhimanyu
    Satpati, Ashis Kumar
    Kumar, Vikram
    Kumar, Sanjiv
    ELECTROCHIMICA ACTA, 2015, 167 : 126 - 131
  • [8] Effect of the sol-gel route on the textural characteristics of silica imprinted with Rhodamine B
    Escobar, Cicero de Coelho
    Zimnoch dos Santos, Joao Henrique
    JOURNAL OF SEPARATION SCIENCE, 2014, 37 (07) : 868 - 875
  • [9] Sol-gel process: temperature effect on textural properties of a monophasic hybrid material
    Cerveau, G
    Corriu, RJP
    Framery, E
    CHEMICAL COMMUNICATIONS, 1999, (20) : 2081 - 2082
  • [10] Influence of the synthesis additive on the textural and structural characteristics of sol-gel Al2O3-TiO2
    Escobar, J
    De los Reyes, JA
    Viveros, T
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2000, 39 (03) : 666 - 672
12345