Manganese(II) 9-Molybdomanganate(IV), [Mn(H2O)4]3 · [MnMo9O32] · 2H2O: Synthesis, thermal analysis, IR spectra, and crystal structure

被引：0
|
作者：
G. Z. Kaziev
A. V. Oreshkina
S. Holguin Quinones
V. E. Zavodnik
A. de Ita
T. A. Tripol’skaya
机构：
[1] Moscow State Pedagogical University,Kurnakov Institute of General and Inorganic Chemistry
[2] Universidad Autonoma Metropolitana,undefined
[3] Karpov Research Institute of Physical Chemistry,undefined
[4] Rusian Academy of Sciences,undefined
来源：
Russian Journal of Coordination Chemistry | 2007年 / 33卷
关键词：
Coordination Chemistry; Dioxo; Heteropoly Compound; Crystallization Water Molecule; Ammonium Molybdate Solution;
D O I：
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学科分类号：
摘要：
The [Mn(H2O)4]3 · [MnMo9O32] · 2H2O complex was synthesized and studied by X-ray diffraction, thermogravimetry, powder X-ray diffraction, and IR spectroscopy. The crystals are trigonal: space group R32, a = 14.811(2) Å, c = 14.232(2) Å, V = 2703.7(8) Å3, M = 1848.5, Z = 3, ρ(calcd.) = 3.419 g/cm3.
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页码：826 / 830
页数：4
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