Measurement of the thermodynamic properties of saturated solid solutions of compounds in the Ag-Sn-Se system by the EMF method

被引：0
|
作者：
M. V. Moroz
M. V. Prokhorenko
机构：
[1] National University of Water Management and Nature Resources Use,
[2] Lviv Polytechnic National University,undefined
来源：
Russian Journal of Physical Chemistry A | 2015年 / 89卷
关键词：
Ag-Sn-Se system; inorganic compounds; thermodynamic functions; EMF method;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The dependence of the EMF (E) of galvanic cells Ag|AgI|Ag2GeS3 glass|D on temperature (where Ag, D denotes the electrodes of an electrochemical cell; D represents equilibrium two- and three-phase alloys of the Ag-Sn-Se system; and AgI|Ag2GeS3 glass is a bilayer membrane with purely ionic (Ag+) conductivity) is studied in the range of 480–580 K. Analytical equations of E(T) are used to calculate the values of the thermodynamic functions of saturated solid solutions of the SnSe, β-Ag2Se, AgSnSe2, and Ag8SnSe6 phases of the Ag-Sn-Se system in the standard state.
引用
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页码：1325 / 1329
页数：4
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