Optimization of Microwave-Assisted Preparation of TPA from Waste PET Using Response Surface Methodology

Terephthalic acid (TPA) was prepared from waste polyethylene terephthalate by microwave-assisted depolymerization with TOMAB as catalyst, the structure and properties of TPA were elucidated by using physico-chemical and spectroscopic methods. Single-factors experiments demonstrated that the TPA yield was affected significantly by the factors of catalyst and alkali amount, depolymerization temperature and time. The effects of variables, including catalyst and alkali amount, depolymerization temperature and time, on the TPA yield were evaluted by response surface methodology with a Box-Behnken design. The modified and verified experiments were completed after considering product performance and actual operation, the optimum parameters were determined to be TOMAB 2.7 g, 15% NaOH 260 mL, temperature 85 °C, degradation time 2.2 h. Under these conditions, the average yield of TPA in three replicated experiments is 97.53%, and this value is not significantly different from the value of 98.59% predicted by the model. These results demonstrate that this method is feasible.