Selective monoalkylation of phosphorus-substituted CH acids with (bromomethyl)- and 1,4-bis(bromomethyl)benzenes

被引：0
|
作者：
I. L. Odinets
O. I. Artyushin
S. V. Lenevich
G. V. Bodrin
K. A. Lyssenko
I. V. Fedyanin
P. V. Petrovskii
T. A. Mastryukova
机构：
[1] Russian Academy of Sciences,A. N. Nesmeyanov Institute of Organoelement Compounds
来源：
Russian Chemical Bulletin | 2004年 / 53卷
关键词：
CH acids; phosphorylacetonitriles; thiophosphorylacetonitriles; alkylation; (bromomethyl)benzene; 1,4-bis(bromomethyl)benzene; phase transfer catalysis; X-ray diffraction analysis;
D O I：
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中图分类号：
学科分类号：
摘要：
C-Alkylation of phosphorus-substituted CH acids with various substituted (bromomethyl)arenes under phase transfer catalysis conditions (K2CO3/MeCN) proceeds with high selectivity (75—100%) as monoalkylation.
引用
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页码：219 / 227
页数：8
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