Self-Consistent Calculation of the Compressibility and Viscosity of Dense Gases in the Lattice-Gas Model

被引:0
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作者
V. N. Komarov
Yu. K. Tovbin
机构
[1] Karpov Institute of Physical Chemistry,
来源
High Temperature | 2003年 / 41卷
关键词
Oxygen; Viscosity; Experimental Data; Statistical Physic; Compressibility;
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摘要
A self-consistent calculation is performed of generalized diagrams of compressibility and shear viscosity of simple gases in a wide range of pressure (from rarefied states to 10Pc) and temperature (from subcritical to supercritical) on the basis of unified potential functions of interparticle interaction. A modified lattice-gas model is used which takes into account the nonideality of gases, the eigenvolume of atoms, and interactions between atoms in a quasi-chemical approximation conserving the effects of direct correlations of short-range order. The calculation results are compared with generalized diagrams of compressibility and viscosity constructed by experimental data. Quantitative agreement is obtained with experimental data for neon and oxygen.
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页码:181 / 188
页数:7
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