Mild and highly regioselective synthesis of biaryl acids via Rh (I)-catalyzed cross-dehydrogenative coupling of benzoic acids using sodium chlorite as oxidant

被引：0
|
作者：
Yun Liu
Youquan Zhu
Chaojun Li
机构：
[1] McGill University,Department of Chemistry, FQRNT Center for Green Chemistry and Catalysis
[2] Jiangsu Normal University,Department of Chemistry and Chemical Engineering
来源：
Frontiers of Chemical Science and Engineering | 2018年 / 12卷
关键词：
biaryl acids; cross-dehydrogenative coupling; rhodium-catalyzed;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A mild and efficient synthesis for the biaryl acids via rhodium-catalyzed cross-dehydrogenative coupling reaction has been developed. This novel protocol with sodium chlorite as an oxidant featured many advantages such as mild reaction conditions, high regioselectivity, tolerance of various functional groups, and good to excellent yields.
引用
收藏
页码：3 / 8
页数：5
相关论文
共 20 条
  • [1] Mild and highly regioselective synthesis of biaryl acids via Rh (I)-catalyzed cross-dehydrogenative coupling of benzoic acids using sodium chlorite as oxidant
    Liu, Yun
    Zhu, Youquan
    Li, Chaojun
    FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING, 2018, 12 (01) : 3 - 8
  • [2] Co(II)-Catalyzed Regioselective Cross-Dehydrogenative Coupling of Aryl C-H Bonds with Carboxylic Acids
    Lan, Jianyong
    Xie, Haisheng
    Lu, Xiaoxia
    Deng, Yuanfu
    Jiang, Huanfeng
    Zeng, Wei
    ORGANIC LETTERS, 2017, 19 (16) : 4279 - 4282
  • [3] Transition-Metal-Free Cross-Dehydrogenative Coupling of Ethyl Arylacetates with Benzoic/Cinnamic Acids: A Practical Synthesis of α-Acyloxy Esters
    Sharma, Anup Kumar
    Kumar, Promod
    Vishwakarma, Ramesh Kumar
    Singh, Krishna Nand
    ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2018, 7 (04) : 688 - 691
  • [4] COPPER CORROLE CATALYZED ESTERIFICATION OF C(sp3)-H WITH CARBOXYLIC ACIDS VIA CROSS-DEHYDROGENATIVE COUPLING REACTION
    Liu, Zhao-Yang
    Peng, Wei-Yu
    Akram, Waseem
    Lai, Jia-Wei
    Zhang, Hao
    Liu, Hai-Yang
    HETEROCYCLES, 2021, 102 (05) : 860 - 870
  • [5] Pd-Catalyzed Homo Cross-Dehydrogenative Coupling of 2-Arylpyridines by Using I2 as the Sole Oxidant
    Liu, Wenbo
    Zhu, Youquan
    Li, Chao-Jun
    SYNTHESIS-STUTTGART, 2016, 48 (11): : 1616 - 1621
  • [6] Palladium (II)-Catalyzed Decarboxylative Cross-Dehydrogenative Coupling: Direct Synthesis of meta-Substituted Biaryls from Aromatic Acids
    Pu, Fan
    Zhang, Lin-Yan
    Liu, Zhong-Wen
    Shi, Xian-Ying
    ADVANCED SYNTHESIS & CATALYSIS, 2018, 360 (14) : 2644 - 2649
  • [7] Rhodaelectro-Catalyzed Decarboxylative Cross-Dehydrogenative Coupling of Indole-3-carboxylic Acids and Olefins via Weakly Coordinating Carboxyl Groups
    Zhang, Jiaqi
    Xu, Weijie
    Zhuang, Weihui
    Chen, Ximan
    Zhang, Xiaofeng
    Huang, Qiufeng
    JOURNAL OF ORGANIC CHEMISTRY, 2023, 88 (21): : 15198 - 15208
  • [8] SYNTHESIS OF UNSYMMETRICAL BIARYL KETONES VIA PALLADIUM-CATALYZED CARBONYLATIVE CROSS-COUPLING REACTION OF ARYLBORONIC ACIDS WITH IODOARENES
    ISHIYAMA, T
    KIZAKI, H
    MIYAURA, N
    SUZUKI, A
    TETRAHEDRON LETTERS, 1993, 34 (47) : 7595 - 7598
  • [9] Iron-Catalyzed Cross-Dehydrogenative Coupling Esterification of Unactive C(sp3)-H Bonds with Carboxylic Acids for the Synthesis of α-Acyloxy Ethers
    Zhao, Jincan
    Fang, Hong
    Zhou, Wei
    Han, Jianlin
    Pan, Yi
    JOURNAL OF ORGANIC CHEMISTRY, 2014, 79 (09): : 3847 - 3855
  • [10] Copper-catalyzed cross-dehydrogenative coupling of N-arylacrylamides with chloroform using tert-butyl peroxybenzoate as oxidant for the synthesis of trichloromethylated 2-oxindoles
    Chan, Chun-Wo
    Lee, Pui-Yiu
    Yu, Wing-Yiu
    TETRAHEDRON LETTERS, 2015, 56 (20) : 2559 - 2563
12