Cp*MCpMoFe(CO)7(μ3-S), Cp*MoCpMFe(CO)7(μ3-S) (M = W, Mo) and Cp*WCp*MoFe(CO)7(μ3-S). Crystal structure of CpMoCp*WFe(CO)7(μ3-S)

被引：0
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作者：
Feng Xu
Yong-Mei Chen
Shi-Yan Yang
Wen-Hua Sun
Kai-Bei Yu
机构：
[1] Chinese Academy of Sciences,Institute of Photographic Chemistry
[2] Lanzhou Institute of Chemical Physics,State Key Laboratory for Oxo Synthesis and Selective Oxidation
[3] Chinese Academy of Sciences,Chengdu Centre of Analysis and Measurement
[4] Chinese Academy of Sciences,undefined
来源：
Transition Metal Chemistry | 2000年 / 25卷
关键词：
Spectroscopy; Physical Chemistry; Crystal Structure; Inorganic Chemistry; Structure Analysis;
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摘要：
CpMoFeCo(CO)7(μ3-S) reacts with Cp*M(CO)3Cl or CpM(CO)3Cl (M = W, Mo) to gave the mixed-metal clusters Cp*WCpMoFe(CO)7(μ3-S) (1), Cp*MoCpMoFe(CO)7(μ3-S) (2), CpWCp*MoFe(CO)7(μ3-S) (3), CpMoCp*MoFe(CO)7(μ3-S) (4) and Cp*WCp*MoFe(CO)7(μ3-S) (5). The title clusters have been characterized by i.r., 1H/13C-n.m.r. spectroscopy and their compositions have been confirmed by elemental analyses. The X-ray crystal structure analysis shows the two independent enantiomeric molecules of clusters (1) in one crystal structure unit.
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页码：108 / 111
页数：3
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