Synthesis and structure of [(nitrito-O,O′) bis(di-2-pyridylamine)copper(II)] nitrite

被引：0

作者：

Alvin A. Holder

Robert T. Stibrany

Nadejda Bolotina

Martin Hall

Vince C.R. Payne

Kristin Kirschbaum

A. Alan Pinkerton

Anthony M. Newton

机构：

[1] Virginia Polytechnic Institute and State University,Department of Chemistry

[2] The State University of New Jersey,Department of Chemistry and Chemical Biology, Rutgers

[3] dCollege of Arts and Sciences,Department of Chemistry

[4] The University of Toledo,Department of Biological and Chemical Sciences

[5] The University of the West Indies,undefined

[6] Cave Hill Campus,undefined

来源：

Journal of Chemical Crystallography | 2004年 / 34卷

关键词：

Nitrite; copper(II); di-2-pyridylamine; hydrogen bonding;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The synthesis and molecular structure of the title compound, [(nitrito-O,O′) (dpa)2Cu(II)] (NO2), 1, is reported. Compound 1 crystallized in the orthorhombic space group Pccn with a = 11.397(5) Å, b = 12.256(6) Å, c = 14.876(8) Å, and V = 2077.9(17) Å3 with Z = 4. The distorted octahedral copper(II) cations are linked through a hydrogen-bonded polymer network. The polymer network is formed through the amine N–H of the cations and hydrogen bonded to the N–H⋅⋅⋅O nitrite anions.

引用

页码：383 / 386

页数：3

共 50 条

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