Naphthalene hydrogenation over nickel–tungsten sulfide catalysts synthesized in situ from DMSO–hydrocarbon medium emulsions

被引：0
|
作者：
I. A. Sizova
S. V. Antonov
S. I. Serdyukov
A. L. Maksimov
机构：
[1] Russian Academy of Sciences,Topchiev Institute of Petrochemical Synthesis
[2] Moscow State University,Faculty of Chemistry
来源：
Petroleum Chemistry | 2017年 / 57卷
关键词：
nickel–tungsten sulfide catalysts; hydrodearomatization; in situ synthesis of catalysts; nonaqueous emulsions; DMSO;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A method for synthesizing unsupported nickel–tungsten sulfide hydrodearomatization catalysts by breaking SPAN-80 surfactant-stabilized nonaqueous emulsions of solutions of different precursors in dimethyl sulfoxide (DMSO) in situ in a hydrocarbon medium has been first studied using ammonium thiotungstate (NH4)2WS4 and 1-butyl-1-methylpiperidinium nickel thiotungstate [BMPip]2Ni[WS4]2 as precursors and nickel nitrate hexahydrate as a nickel source. The synthesized nickel–tungsten catalysts have been characterized by TEM and XPS. The catalytic activity of the in situ synthesized Ni–W particles in naphthalene hydrogenation has been studied at temperatures of 350–400°C and a hydrogen pressure of 5.0 MPa.
引用
收藏
页码：66 / 70
页数：4
相关论文
共 50 条
  • [1] Naphthalene hydrogenation over nickel-tungsten sulfide catalysts synthesized in situ from DMSO-hydrocarbon medium emulsions
    Sizova, I. A.
    Antonov, S. V.
    Serdyukov, S. I.
    Maksimov, A. L.
    PETROLEUM CHEMISTRY, 2017, 57 (01) : 66 - 70
  • [2] Nickel-tungsten sulfide aromatic hydrocarbon hydrogenation catalysts synthesized in situ in a hydrocarbon medium
    I. A. Sizova
    S. I. Serdyukov
    A. L. Maksimov
    Petroleum Chemistry, 2015, 55 : 470 - 480
  • [3] Nickel-tungsten sulfide aromatic hydrocarbon hydrogenation catalysts synthesized in situ in a hydrocarbon medium
    Sizova, I. A.
    Serdyukov, S. I.
    Maksimov, A. L.
    PETROLEUM CHEMISTRY, 2015, 55 (06) : 470 - 480
  • [4] Nickel–Tungsten and Nickel–Molybdenum Sulfide Diesel Hydrocarbon Hydrogenation Catalysts Synthesized in Pores of Aromatic Polymer Materials
    R. A. Batryshin
    D. A. Makeeva
    L. A. Kulikov
    Yu. S. Kardasheva
    A. L. Maksimov
    E. A. Karakhanov
    Petroleum Chemistry, 2019, 59 : 575 - 580
  • [5] Hydrofining of light cycle oil over in situ synthesized nickel–tungsten sulfide catalysts
    I. A. Sizova
    A. L. Maksimov
    Petroleum Chemistry, 2016, 56 : 510 - 521
  • [6] Nickel–molybdenum sulfide naphthalene hydrogenation catalysts synthesized by the in situ decomposition of oil-soluble precursors
    I. A. Sizova
    A. L. Maksimov
    Petroleum Chemistry, 2017, 57 : 595 - 599
  • [7] Hydrofining of light cycle oil over in situ synthesized nickel-tungsten sulfide catalysts
    Sizova, I. A.
    Maksimov, A. L.
    PETROLEUM CHEMISTRY, 2016, 56 (06) : 510 - 521
  • [8] Nickel-Molybdenum Sulfide Naphthalene Hydrogenation Catalysts Synthesized by the In Situ Decomposition of Oil-Soluble Precursors
    Sizova, I. A.
    Maksimov, A. L.
    PETROLEUM CHEMISTRY, 2017, 57 (07) : 595 - 599
  • [9] Nickel-Tungsten and Nickel-Molybdenum Sulfide Diesel Hydrocarbon Hydrogenation Catalysts Synthesized in Pores of Aromatic Polymer Materials
    Batryshin, R. A.
    Makeeva, D. A.
    Kulikov, L. A.
    Kardasheva, Yu. S.
    Maksimov, A. L.
    Karakhanov, E. A.
    PETROLEUM CHEMISTRY, 2019, 59 (06) : 575 - 580
  • [10] Hydrogenation of cyclohexanone on nickel-tungsten sulfide catalysts
    Olivas, A
    Samano, EC
    Fuentes, S
    APPLIED CATALYSIS A-GENERAL, 2001, 220 (1-2) : 279 - 285
12345