Palladium complex of 6-(2-hydroxy-5-methylphenyl)-3-(pyridin-2-yl)-1,2,4-triazin-5(2H)-one: Synthesis, structure, and catalytic activity

被引：0
|
作者：
A. V. Mekhaev
A. V. Pestov
P. A. Slepukhin
Yu. G. Yatluk
M. G. Pervova
M. A. Samorukova
O. N. Chupakhin
机构：
[1] Russian Academy of Sciences,Postovskii Institute of Organic Synthesis, Ural Division
来源：
Russian Journal of Organic Chemistry | 2011年 / 47卷
关键词：
Butyl Acrylate; Palladium Complex; Heck Reaction; Iodobenzene; Triazine Ring;
D O I：
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摘要：
Palladium(II) complex with 6-(2-hydroxy-5-methylphenyl)-3-(pyridin-2-yl)-1,2,4-triazin-5(2H)-one was synthesized for the first time. The ligand was prepared from 3-(pyridin-2-yl)-1,2,4-triazin-5(2H)-one and 4-methylphenol via nucleophilic substitution of hydrogen (SNH reaction). The complex was readily soluble in basic medium, and it effectively catalyzed Mizoroki-Heck reaction.
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页码：1366 / 1369
页数：3
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