α- and β-diphenylphosphorylated secondary alkanols: I. general method of synthesis and extraction properties towards f-elements

被引：0
|
作者：
E. I. Goryunov
A. G. Matveeva
A. M. Safiulina
I. B. Goryunova
G. V. Bodrin
V. K. Brel
机构：
[1] Russian Academy of Sciences,Nesmeyanov Institute of Organoelement Compounds
[2] Open Joint-Stock Company,Uralchem United Chemical Company
来源：
Russian Journal of General Chemistry | 2016年 / 86卷
关键词：
-diphenylphosphorylalkanones; sodium borohydride; secondary ; -diphenylphosphorylalkanols; lanthanides, extraction;
D O I：
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学科分类号：
摘要：
A simple and effective general method of synthesis of α- and β-diphenylphosphorylated secondary alkanols by the reduction of the corresponding phosphorylalkanones with NaBH4 was developed. The extraction properties of the resulting phosphorylalkanols Ph2P(O)(CR2)nCH2CH(OH)Me (n = 0, 1; R = H, Me) were studied in the recovery of f-elements (LaIII, NdIII, HoIII, YbIII, UVI, ThIV) from nitric acid solutions into chloroform and compared with those of both related phosphorylketones and known extractants (n-BuO)3PO, (n-C8H17)3PO, and Ph2P(O)CH2C(O)N(n-Bu)2.
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页码：629 / 638
页数：9
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