Selective oxidation of octadecan-1-ol to octadecanoic acid over Co 3O4/SiO2 catalysts

被引：0
|
作者：
Hong Z. [1 ]
Tiexin C. [1 ]
Yingli B. [1 ]
Guangdong Z. [1 ]
Kaiji Z. [1 ]
机构：
[1] College of Chemistry, Jilin University
来源：
Reaction Kinetics and Catalysis Letters | 2004年 / 81卷 / 1期
基金：
中国国家自然科学基金;
关键词：
Co[!sub]3[!/sub]O[!sub]4[!/sub]SiO[!sub]2[!/sub] catalysts; Octadecan-1-ol; Octadecanoic acid; Selective oxidation;
D O I：
10.1023/B:REAC.0000016511.39679.9e
中图分类号：
学科分类号：
摘要：
Factors (reaction temperature, reaction time, flow rate of oxygen, amount of catalyst, etc.) influencing the catalytic properties of Co3O 4/SiO2 catalyst in the oxidation octadecan-1-ol to octadecanoic acid were investigated. The catalysts were characterized by means of XRD, FT-IR and N2-adsorption. The experimental results indicate that under the optimal condition the selectivity to octadecanoic acid reached 97.5% over 5% Co3O4/SiO2 catalyst.
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页码：13 / 20
页数：7
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