Photolysis of an alkoxyamine using intramolecular energy transfer from a quinoline antenna—towards photo-induced living radical polymerization

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作者
Atsushi Goto
J. C. Scaiano
Luca Maretti
机构
[1] Kyoto University,Institute for Chemical Research
[2] Uji,Department of Chemistry
[3] University of Ottawa,undefined
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摘要
The photolysis of an alkoxyamine triad comprised of the 1-phenylethyl moiety, 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO) and 2-methyl-3-hydroxy quinoline leads to energy transfer from the quinoline moiety (antenna) and cleavage of the C–O alkoxyamine bond, suggesting its possible applications in low temperature living free radical polymerization.
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页码:833 / 835
页数:2
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