The exchange reaction of hydrogen atoms in the system sterically hindered hydroxylamine-nitroxyl radical

被引：0

作者：

A. D. Malievskii

S. V. Koroteev

机构：

[1] Russian Academy of Sciences,N. N. Semenov Institute of Chemical Physics

来源：

Russian Chemical Bulletin | 1998年 / 47卷

关键词：

hydroxylamine; nitroxyl radical; kinetics; isotope effect; rate constant; abstraction reaction;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The rate constants of the direct and reverse exchange reactions of the hydrogen atom in the system sterically-hindered nitroxyl radical-hydroxylamine of the quinoline, imidazoline, pyrrolidine, and piperidine series as well as diarylhydroxylamine were determined. A scale of the reductive abilities of the hydrolamines was established. A low value of the isotope effect is typical of the reactions of hydrogen exchange in the systems hydroxylamine-nitroxyl radical.

引用

页码：1287 / 1291

页数：4

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