Study on groundwater recharge based on chloride mass balance and hydrochemistry in the irrigated agricultural area, North China Plain

In the North China Plain, water shortage seriously restricts economic development, and agricultural irrigation depends heavily on groundwater extraction. Irrigation water and precipitation may directly recharge groundwater in the irrigated agricultural region. Therefore, calculating the recharge of precipitation and irrigation to groundwater is essential for the sustainable utilization of water resources. Furthermore, determining the transformation relationship of precipitation-soil water-groundwater is helpful to understand the hydrological cycle process better. The average groundwater recharge calculated by the chloride mass balance method is between 66 and 144 mm/year, accounting for only 7–17% of the total precipitation and irrigation water. The hydrogen (2H) and oxygen (18O) isotopes reveal that precipitation only affects soil water in topsoil, and soil water in deep soil is recharged upward by groundwater. The hydrochemical composition of soil water shows high concentrations of salt in unsaturated zones. Infiltration water dissolves salt through the unsaturated zone and carries them into the shallow groundwater, causing the deterioration of shallow groundwater quality. These results contribute to the effective management of groundwater resources and the control of agricultural pollution in groundwater.