Arylation of adamantanamines: II. Palladium-catalyzed amination of dihalobenzenes with adamantylalkanamines

被引：0

作者：

A. D. Averin

M. A. Ulanovskaya

A. K. Buryak

E. N. Savel’ev

B. S. Orlinson

I. A. Novakov

I. P. Beletskaya

机构：

[1] Moscow State University,Faculty of Chemistry

[2] Russian Academy of Sciences,Frumkin Institute of Physical Chemistry and Electrochemistry

[3] Volgograd State Technical University,undefined

来源：

Russian Journal of Organic Chemistry | 2010年 / 46卷

关键词：

BINAP; Anhydrous Dioxane; Bromoaniline; Light Yellow Oily Substance; Xantphos;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Palladium-catalyzed arylation of various (1-adamantyl)alkanamines with isomeric (ortho, meta, and para) bromochloro- and dibromobenzenes was studied. Optimal catalytic systems were found for the synthesis of mono- and diamination products, and the dependences of their yields on the nature of the initial amine and dihalobenzene and on the amount of base were examined. Side amination products were isolated, and paths of their formation were analyzed.

引用

页码：1790 / 1811

页数：21

共 50 条

[1] Arylation of adamantanamines: II. Palladium-catalyzed amination of dihalobenzenes with adamantylalkanamines
Averin, A. D.
Ulanovskaya, M. A.
Buryak, A. K.
Savel'ev, E. N.
Orlinson, B. S.
Novakov, I. A.
Beletskaya, I. P.
[J]. RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2010, 46 (12) : 1790 - 1811
[2] Palladium-catalyzed amination of dihalobenzenes
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[J]. RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2012, 48 (12) : 1495 - 1508
[6] Arylation of adamantanamines: IV. Palladium-catalyzed arylation of amines of adamantane series with isomeric chloroquinolines
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[J]. RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2012, 48 (11) : 1391 - 1406
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