Cobalt tetrasulfophthalocyaninate as a catalyst of the reduction of nitrite with thiourea dioxide

被引:0
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作者
A. S. Pogorelova
S. V. Makarov
E. S. Ageeva
R. Silagi-Dumitresku
机构
[1] Russian Academy of Sciences,Institute of Solution Chemistry
[2] Ivanovo State University of Chemical Technology,undefined
[3] Babes-Bolyai University,undefined
关键词
Nitrite; Sulfite; Kinetic Curve; Dithionite; Reduc Tion;
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摘要
The kinetics of reduction of nitrite with thiourea dioxide in the presence of cobalt tetrasulfophth-alocyaninate was studied. The process was shown to involve the CoII ↔ CoI catalytic cycle. The kinetic parameters of the reduction of CoII and CoI tetrasulfophthalocyaninates were determined
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页码:2050 / 2053
页数:3
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