A Novel Fluorescent Probe for the Highly Selective and Sensitive Detection of Palladium in Aqueous Medium

被引：0
|
作者：
Zhiwei Ma
Xiao Wang
Yanling Sun
Juntao Liu
Yan Tong
Zhijing Liu
机构：
[1] Henan University of Animal Husbandry and Economy,Department of Fundamental Courses
[2] Jinan University,Integarated Chinese and Western Medicine Postdoctoral Research Station, Medical College
[3] Henan Furen Phamaceutical Technology Development Limited Company,undefined
来源：
Journal of Fluorescence | 2016年 / 26卷
关键词：
Fluorescence; Pd; NBD; Tsuji-Trost reaction;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Based on the Pd0-catalyzed Tsuji-Trost allylic oxidative insertion reaction, we developed a fluorescent probe PdL1 for sensing Pd0. As expected, probe PdL1 exhibited high selectivity and excellent sensitivity in both absorbance and fluorescence detection of Pd0 in CH3CH2OH/PBS (10 mM, pH = 7.4, 6:4, v/v) solution. The detection limit was calculated to be as low as 15 nM, which can meet the selective requirements for practical application.
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页码：1917 / 1921
页数：4
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