Cation mobility in modified Li1 + xTi2 − xGax(PO4)3 lithium titanium NASICON phosphates

被引：0
|
作者：
I. Yu. Pinus
I. V. Arkhangel’skii
N. A. Zhuravlev
A. B. Yaroslavtsev
机构：
[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry
[2] Moscow State University,Department of Chemistry
[3] Russian Academy of Sciences,Institute of Solid
来源：
Russian Journal of Inorganic Chemistry | 2009年 / 54卷
关键词：
Correlation Time; Titanium Phosphate; Cation Mobility; Calorimetry Data; Potassium Magnesium;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Li1 +xTi2 − xGax(PO4)3(x= 0−0.2) NASICON double phosphates are prepared and studied by high-temperature X-ray diffraction, 7Li NMR spectroscopy, impedance spectroscopy, and calorimetry. Doping with Ga3+ cations increases cation mobility in LiTi2(PO4)3. Ion conductivity, NMR spectroscopy, and calorimetry data imply the occurrence of a phase transition in LiTi2(PO4)3 and in products of partial gallium-for-titanium substitution.
引用
收藏
页码：1173 / 1176
页数：3
相关论文
共 50 条
  • [1] Cation mobility in modified Li1 − xTi2 − xNbx(PO4)3 lithium titanium NASICON phosphates
    I. Yu. Pinus
    I. A. Stenina
    A. I. Rebrov
    N. A. Zhuravlev
    A. B. Yaroslavtsev
    Russian Journal of Inorganic Chemistry, 2009, 54 : 1177 - 1180
  • [2] Cation mobility in Li1 + xTi2 − xCrx(PO4)3 NASICON-type phosphates
    A. I. Svitan’ko
    S. A. Novikova
    D. V. Safronov
    A. B. Yaroslavtsev
    Inorganic Materials, 2011, 47 : 1391 - 1395
  • [3] Cation mobility in Li1+xTi2-xCrx(PO4)3 NASICON-type phosphates
    Svitan'ko, A. I.
    Novikova, S. A.
    Safronov, D. V.
    Yaroslavtsev, A. B.
    INORGANIC MATERIALS, 2011, 47 (12) : 1391 - 1395
  • [4] Cation mobility in Li1 + xHf2 − xScx(PO4)3 NASICON-type phosphates
    Yu. O. Korepina
    L. Sh. Bigeeva
    A. B. Il’in
    A. I. Svitan’ko
    S. A. Novikova
    A. B. Yaroslavtsev
    Inorganic Materials, 2013, 49 : 283 - 287
  • [5] Cation mobility in modified Li1+x Ti2-x Ga x (PO4)3 lithium titanium NASICON phosphates
    Pinus, I. Yu.
    Arkhangel'skii, I. V.
    Zhuravlev, N. A.
    Yaroslavtsev, A. B.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2009, 54 (08) : 1173 - 1176
  • [6] Cation mobility in modified Li1-x Ti2-x Nb x (PO4)3 lithium titanium NASICON phosphates
    Pinus, I. Yu.
    Stenina, I. A.
    Rebrov, A. I.
    Zhuravlev, N. A.
    Yaroslavtsev, A. B.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2009, 54 (08) : 1177 - 1180
  • [7] Microstructure and ion transport in Li1 + xTi2 − xMx(PO4)3 (M = Cr, Fe, Al) NASICON-type materials
    A. I. Svitan’ko
    S. A. Novikova
    I. A. Stenina
    V. A. Skopets
    A. B. Yaroslavtsev
    Inorganic Materials, 2014, 50 : 273 - 279
  • [8] Cation mobility in Li1+xHf2-xScx(PO4)3 NASICON-type phosphates
    Korepina, Yu. O.
    Bigeeva, L. Sh.
    Il'in, A. B.
    Svitan'ko, A. I.
    Novikova, S. A.
    Yaroslavtsev, A. B.
    INORGANIC MATERIALS, 2013, 49 (03) : 283 - 287
  • [9] Phase transformations and cation mobility in NASICON lithium zirconium double phosphates Li1±xZr2-xMx(PO4)3 (M = Sc, Y, In, Nb, Ta)
    Stenina, IA
    Kislitsyn, MN
    Pinus, IY
    Arkhangel'skii, IV
    Zhuravlev, NA
    Yaroslavtsev, AB
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2005, 50 (06) : 906 - 911
  • [10] Lithium mobility in titanium based Nasicon Li1+xTi2-xAlx(PO4)3 and LiTi2-xZrx(PO4)3 materials followed by NMR and impedance spectroscopy
    Arbi, K.
    Rojo, J. M.
    Sanz, J.
    JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2007, 27 (13-15) : 4215 - 4218
12345