Solvophobic effects in binary nonaqueous mixtures

被引：0
|
作者：
M. V. Kulikov
A. M. Zaichikov
机构：
[1] Russion Academy of Sciences,Institute of Chemistry of Non
[2] Ivanova State Academy of Chemistry and Technology,Aqueous Solution
来源：
Russian Chemical Bulletin | 1997年 / 46卷
关键词：
aqueous and nonaqueous solutions; amides; alcohols; acetonitrile; McMillan—Mayer theory; coefficients of binary and ternary interactions; solvophobic effects; hydrophobic hydroation; criteria for hydrophobicity;
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摘要：
In the framework of the Mc Millan-Mayer theory, the enthalpy, volume, and heat capacity coefficients of binary and ternary interactions of amides, alcohols, and acetonitrile in water and nonaqueous solvents were obtained at various temperatures. No pronounced regularities in changes in the coefficients of multiple interactions observed in aquous solutions were found for nonaqueous solutions of the substances studied. None of the considered coefficients can be used as a criterion for solvophobicity.
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页码：1513 / 1517
页数：4
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