Iron(III) and Cobalt(III) Complexes with Oxalate and Phenanthroline: Synthesis, Crystal Structure, Spectroscopy Properties and Magnetic Properties

被引：0
|
作者：
Jawher Abdelhak
Sawssen Namouchi Cherni
Mongi Amami
Hlil El Kébir
Mohamed Faouzi Zid
Ahmed Driss
机构：
[1] Université de Tunis El Manar,Laboratoire de Matériaux et Cristallochimie, Département de Chimie, Faculté des Sciences de Tunis
[2] Université de Tunis El Manar,Unité de Chimie des Matériaux et de l’Environnement, ISSBAT
[3] Institut Néel CNRS,undefined
来源：
Journal of Superconductivity and Novel Magnetism | 2014年 / 27卷
关键词：
Iron(III) and cobalt(III) complexes; Crystal structure; Thermal behavior; Visible and ultraviolet spectrometers; Magnetic properties;
D O I：
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学科分类号：
摘要：
We report herein the synthesis and physicochemical characterization of two mixed-ligand complexes of the following stoichiometric formulae: [Fe(phen)2(ox)](NO3)⋅2H2O (1) and [Co(phen)2(ox)](NO3)⋅4H2O (2) (as phen: 1,10-orthophenanthroline; ox: oxalate dianion). Both compounds have been prepared by slow evaporation at room temperature and characterized by single-crystal X-ray diffraction. They have been characterized by IR and UV–Vis spectra and thermoanalysis (TG and DTA)
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页码：1693 / 1700
页数：7
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