Extraction of ruthenium(III) by dihexyl sulfoxide from hydrochloric solutions

被引：0
|
作者：
N. G. Afzaletdinova
L. M. Ryamova
Yu. I. Murinov
R. V. Kunakova
机构：
[1] Russian Academy of Sciences,Institute of Organic Chemistry, Ufa Scientific Center
[2] Ufa State Institute of Service,undefined
来源：
Russian Journal of Inorganic Chemistry | 2006年 / 51卷
关键词：
Ruthenium; Coordination Sphere; Electronic Absorption Spectrum; Distribution Ratio; Oxygen Donor Atom;
D O I：
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学科分类号：
摘要：
The extraction of ruthenium(III) by dihexyl sulfoxide (DHSO) from hydrochloric solutions is studied. Ruthenium(III) is first extracted by a hydration/solvation mechanism followed by the incorporation of extractant molecules into the inner coordination sphere of the ruthenium(III) ion. The composition of the extracted compound is suggested proceeding from the resuls of electronic, 1H NMR spectroscopy, IR spectroscopy, and elemental analysis.
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页码：1139 / 1145
页数：6
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