Additive-Salt Effect on Low Detection Limit and Slope Sensitivity in Response of Potassium- and Sodium-Selective Neutral Carrier Based Electrodes and Their Liquid-Membrane Based Ion-Sensitive Field-Effect Transistor

被引:0
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作者
Shin-ichi Wakida
Takashi Masadome
Toshihiko Imato
Yasuhiko Shibutani
Kenji Yakabe
Toshiyuki Shono
Yasukazu Asano
机构
[1] Osaka National Research Institute,1Department of Energy and the Environment
[2] Agency of Industrial Science and Technology,Department of Chemical Science and Engineering
[3] Ministry of International Trade and Industry,Department of Chemical Science and Technology, Faculty of Engineering
[4] Ariake National College of Technology,Department of Applied Chemistry
[5] Kyushu University,Laboratory of Chemistry, Department of General Education
[6] Osaka Institute of Technology,undefined
[7] Asahi,undefined
[8] Ariake National College of Technology,undefined
[9] Omuta,undefined
来源
Analytical Sciences | 1999年 / 15卷
关键词
Additive salts; response behavior; ion-selective electrode; neutral carrier; liquid membrane; potassium and sodium ion-sensitive field-effect transistor;
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学科分类号
摘要
The remarkable effect of additive salts on low detection limits as well as slope sensitivities were observed for the response characteristics of bis(crown) and valinomycin based poly(vinyl chloride) (PVC) membrane electrodes. The low detection limits and the slope sensitivities for bis(crown) and valinomycin based PVC membrane electrodes were improved apparently as the hydrophobicity of the additive salts increases. In order to clarify the effect of additive salts of the PVC membrane electrodes, the response characteristics of liquid-membrane based K+ and Na+-ISEs, which were fabricated by using micro-ion-sensitive field-effect transistors (µ-ISFETs), were evaluated. The low detection limits and the slope sensitivities in the responses of the neutral-carrier based K+ and Na+-µ-ISFETs also changed remarkably with the kind as well as the concentration of the additive salts.
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页码:47 / 51
页数:4
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