Palladium-catalyzed heck and suzuki coupling in glycerol

被引：0
|
作者：
A. Wolfson
C. Dlugy
机构：
[1] Sami Shamoon College of Engineering,Green Processes Center, Chemical Engineering Department
来源：
Chemical Papers | 2007年 / 61卷
关键词：
Pd cross coupling; Heck reaction; Suzuki reaction; green solvent; liquid—liquid extraction;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The Heck coupling of halobenzenes with various alkenes and the Suzuki cross coupling of halobenzenes with phenylboronic acid were successfully performed in glycerol as the reaction solvent using homogeneous and heterogeneous palladium catalysts. Glycerol is a renewable and recyclable green solvent that is able to dissolve organic substrates, inorganic bases, and palladium complexes, and that allows easy isolation of the reaction product by simple extraction with glycerol-immiscible solvents such as diethyl ether, hexane, and dichloromethane.
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页码：228 / 232
页数：4
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