Chiral copper-Schiff base catalyst for asymmetric henry reaction

被引:0
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作者
Yong-guang Gao
Na Chen
Hua-jiang Wu
Xin-sheng Li
机构
[1] Zhejiang Normal University,Department of Chemistry
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关键词
Benzaldehyde; Base Complex; Nitromethane; Salicylaldehydes; Amino Alcohol;
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学科分类号
摘要
Five copper-Schiff base complexes were synthesized conveniently from copper(II) acetate monohydrate, salicylaldehydes, and amino alcohols. The complexes were shown to be effective as catalysts in the asymmetric Henry reaction affording nitro alkanols in up to 98% yield with moderate and good enantiomeric excess (up to ee 38.6%).
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页码:1754 / 1756
页数:2
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