Oxidation of Cyclohexene in the Presence of Alkanes in a Barrier Discharge Plasma

被引：0
|
作者：
S. V. Kudryashov
A. Yu. Ryabov
E. E. Sirotkina
G. S. Shchegoleva
机构：
[1] Institute of Petroleum Chemistry,Siberian Division, Russian Academy of Sciences
来源：
High Energy Chemistry | 2003年 / 37卷
关键词：
Oxidation; Physical Chemistry; Hexane; Alkane; Partial Pressure;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The oxidation of cyclohexene mixtures with hexane, octane, decane, and cyclohexane was studied in a dielectric-barrier discharge reactor. It was shown that a decrease in the partial pressure of cyclohexene in the mixture resulted in a significant increase in the yield of cyclohexene oxide to ∼75%, with the composition of oxidation products being the same as in the oxidation of individual compounds. A plausible mechanism of the reaction is proposed.
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页码：184 / 186
页数：2
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