Effect of pH value on stress corrosion cracking of X70 pipeline steel in acidic soil environment

被引:0
|
作者
Zhiyong Liu
Cuiwei Du
Xin Zhang
Fuming Wang
Xiaogang Li
机构
[1] University of Science and Technology Beijing,Corrosion and Protection Center
[2] Ministry of Environmental Protection of China,Nuclear and Radiation Safety Center
[3] University of Science and Technology Beijing,School of Metallurgical and Ecological Engineering
关键词
X70 pipeline steel; Soil environment; pH; Stress corrosion cracking;
D O I
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中图分类号
学科分类号
摘要
The effect of pH value on the stress corrosion cracking (SCC) of API X70 pipeline steel in simulated acidic soil solutions was investigated by using slow strain rate test, electrochemical polarization curves, electrochemical impedance spectroscopy, and scanning electron microscopy. pH plays an important role in the susceptibility and electrochemical mechanism of SCC. The pH higher than 5 has no significant effect on electrochemical processes. By contrast, the pH lower than 5 intensifies cathodic hydrogen evolution reactions, thus increasing the cathodic current and corrosion potential. Under different pH values, the SCC mechanism of X70 pipeline steel varies among anodic dissolution (AD), hydrogen embrittlement (HE), and the combination of AD and HE (AD + HE) with variations of applied potential. At −850 mVSCE, the SCC mechanism is HE if pH is less than 4 or AD + HE if pH value is more positive.
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页码:489 / 496
页数:7
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