Understanding the Formation and Evolution of Oxide Inclusions in Si-Deoxidized Spring Steel

To illustrate the mechanism of the formation and evolution of inclusions in Si-deoxidized spring steel, pilot trials and systematic samplings were conducted, and detailed information about the inclusion density, morphology and composition was elucidated by electron probe X-ray microanalysis. The steel samples were collected from the vacuum degassing furnace, tundish furnace and spring rods after hot rolling. Based on the relationship between the mass ratio of XCaO/XSiO2\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$ X_{{\left( {\text{CaO}} \right)}} /X_{{\left( {{\text{SiO}}_{ 2} } \right)}} $$\end{document} and diameters of inclusions, CaO-SiO2 inclusions were found to be formed by the coalescence between SiO2 and CaO-SiO2 inclusions. Most CaO-SiO2 inclusions > 10 μm were located in the melilite areas with liquidus temperatures < 1400 °C. The Al2O3-SiO2-CaO inclusions in the steel samples from the vacuum degassing and tundish furnaces were considered to be formed by reduction of CaO-SiO2 inclusions by Al dissolved in steel. The increased number density of Al2O3-SiO2-CaO inclusions in spring rods was primarily attributed to the entrapment of Na2O-contained mould flux particles and inclusions crushed after hot rolling. Many Al2O3-SiO2-MnO and SiO2-MnO inclusions were observed in tundish furnace samples, which originated from inherent reactions between [Al], [Si], [Mn] and [O] in the molten steel. The SiO2 precipitation of Al2O3-SiO2-MnO inclusions was attributed to the solubility decrease during the solidification process with temperature drop.