Reaction between glycerol and acetone in the presence of ethylene glycol

被引：0
|
作者：
D. N. Ramazanov
A. Dzhumbe
A. I. Nekhaev
V. O. Samoilov
A. L. Maximov
E. V. Egorova
机构：
[1] Russian Academy of Sciences,Topchiev Institute of Petrochemical Synthesis
[2] Lomonosov Moscow State University of Fine Chemical Technology,undefined
来源：
Petroleum Chemistry | 2015年 / 55卷
关键词：
acetalization; glycerol; ethylene glycol; zeolites; cation-exchange resins;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The acetalization of glycerol with acetone in the presence of ethylene glycol over KU-2 and Amberlyst 70 cation-exchange resins and β and Y zeolites has been studied. It has been shown that the rates of conversion of glycerol and ethylene glycol over the cation-exchange resins are significantly lower than over the zeolites. The rates of conversion of the polyols over the β zeolite are lower than over the Y zeolite. Conditions for the complete conversion of glycerol to acetal have been found. The turnover number (TON) per acid site have been determined; for example, TON = 640 min−1 for glycerol over the Y zeolite. The activation energy is 19.9 and 46.2 kJ/mol for ethylene glycol and glycerol, respectively.
引用
收藏
页码：140 / 145
页数：5
相关论文
共 50 条
  • [1] Reaction between glycerol and acetone in the presence of ethylene glycol
    Ramazanov, D. N.
    Dzhumbe, A.
    Nekhaev, A. I.
    Samoilov, V. O.
    Maximov, A. L.
    Egorova, E. V.
    PETROLEUM CHEMISTRY, 2015, 55 (02) : 140 - 145
  • [2] OLIGOMERIZATION OF GLYCEROL AND ETHYLENE-GLYCOL IN PRESENCE OF CUMENE PEROXIDE
    KAJDAS, C
    KWIATEK, A
    FETTE SEIFEN ANSTRICHMITTEL, 1980, 82 (08): : 324 - 324
  • [3] THE BIURET REACTION OF PROTEINS IN THE PRESENCE OF ETHYLENE GLYCOL
    MEHL, JW
    JOURNAL OF BIOLOGICAL CHEMISTRY, 1945, 157 (01) : 173 - 180
  • [4] Comparison between glycerol and ethylene glycol for dog semen cryopreservation
    Rota, A
    Milani, C
    Cabianca, G
    Martini, M
    THERIOGENOLOGY, 2006, 65 (09) : 1848 - 1858
  • [5] A CASE OF APPARENT PHYSIOLOGICAL COMPETITION BETWEEN ETHYLENE GLYCOL AND GLYCEROL
    JACOBS, MH
    BIOLOGICAL BULLETIN, 1954, 107 (02): : 314 - 315
  • [6] Etherification of glycerol and ethylene glycol by isobutylene
    Klepacova, Katarina
    Mravec, Dusan
    Kaszonyi, Alexander
    Bajus, Martin
    APPLIED CATALYSIS A-GENERAL, 2007, 328 (01) : 1 - 13
  • [7] Polyaniline prepared in ethylene glycol or glycerol
    Konyushenko, Elena N.
    Reynaud, Stephanie
    Pellerin, Virginie
    Trchova, Miroslava
    Stejskal, Jaroslav
    Sapurina, Irina
    POLYMER, 2011, 52 (09) : 1900 - 1907
  • [8] The SAFT for prediction of hydrate formation conditions of gas mixtures in the presence of methane, glycerol, ethylene glycol, and triethylene glycol
    Kou, Xuan
    Li, Xiao-Sen
    ENERGY, 2019, 188
  • [9] Solubility of valdecoxib in the presence of glycerol, propylene glycol, and poly(ethylene glycol) 400 at (298.15, 303.15, and 308.15) K
    Liu, CS
    Desai, KGH
    Chen, XG
    Tang, XX
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2005, 50 (05): : 1736 - 1739
  • [10] Reduction of Cr6+ to Cr3+ in presence of ethylene glycol and glycerol
    Salem, DMSA
    BULLETIN OF ELECTROCHEMISTRY, 2004, 20 (11): : 511 - 515
12345