Bond dissociation energies of nitroethanes and their radicals

被引：0

作者：

E. A. Miroshnichenko

T. S. Kon’kova

Ya. O. Inozemtsev

V. P. Vorob’eva

Yu. N. Matyushin

机构：

[1] Russian Academy of Sciences,Semenov Institute of Chemical Physics

来源：

Russian Journal of Physical Chemistry B, Focus on Physics | 2008年 / 2卷

关键词：

Enthalpy; Ethane; Nitro Group; Dissociation Energy; Bond Dissociation Energy;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Based on control experiments and published data, the thermochemical characteristics of ethane nitroderivatives in the standard state and in the gas phase were recommended. The dissociation energies of the bonds in polynitroethanes were determined from the energies of the nonvalence interactions of nitro groups with each other and compared to the available kinetic data. The energies of the nonfunctional interaction of nitro groups were used to calculate the dissociation energies of bonds in nitroethyl radicals.

引用

页码：595 / 599

页数：4

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