Aggregation of sodium dodecyl sulfate in poly(ethylene glycol) aqueous solution studied by 1H NMR spectroscopy

被引:0
|
作者
H. Yuan
L. Luo
L. Zhang
S. Zhao
S. Mao
J. Yu
L. Shen
Y. Du
机构
[1] State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics,
[2] Wuhan Institute of Physics and Mathematics,undefined
[3] The Chinese Academy of Sciences,undefined
[4] Wuhan 430071,undefined
[5] China,undefined
[6] Technical Institute of Physics and Chemistry,undefined
[7] The Chinese Academy of Sciences,undefined
[8] Beijing 100101,undefined
[9] China,undefined
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关键词
Sodium dodecyl sulfate Poly(ethylene glycol) Interaction 1H NMR Self-diffusion coefficient Spin-spin relaxation 2D NOESY;
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摘要
1H NMR self-diffusion coefficient, spin–spin relaxation and two-dimensional nuclear Overhauser enhancement spectroscopy measurements of sodium dodecyl sulfate (SDS) in poly(ethylene glycol) (PEG) aqueous solution show that SDS molecules start to self-aggregate at a concentration of 3.3 mM, which is well below the normal critical micellar concentration (cmc). SDS micelles are formed when the cmc is reached with PEG solubilized in their hydrophobic micellar cores.
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页码:479 / 484
页数:5
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