EPR studies of Cu2+-doped bis(saccharinato)bis(pyridine)zinc(II) single crystals

被引：0
|
作者：
E. Bozkurt
I. Kartal
B. Karabulut
O. Z. Yeşilel
机构：
[1] Ondokuz Mayis University,Department of Physics, Faculty of Sciences
[2] Ondokuz Mayis University,Department of Chemistry, Faculty of Sciences
来源：
Applied Magnetic Resonance | 2004年 / 26卷
关键词：
Electron Paramagnetic Resonance; Electron Paramagnetic Resonance Spectrum; Saccharin; Electron Paramagnetic Resonance Study; Spin Hamiltonian Parameter;
D O I：
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学科分类号：
摘要：
The electron paramagnetic resonance spectra of Cu2+ impurities in bis(saccharinato)bis(pyridine)zinc(II) single crystals have been studied at room temperature in three mutually perpendicular planes. The angular variation of the spectra indicates the substitution of the host Zn2+ with Cu2+. Two magnetically inequivalent sites for Cu2+ have been observed. The spectra were fitted to the rhombic spin Hamiltonian. The spin Hamiltonian parameters and the molecular orbital coefficients were evaluated for the two sites. The ground-state wave function of Cu2+ ion in the lattice has been constructed.
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页码：275 / 282
页数：7
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