Galvanostatic charge–discharge tests, 57Fe and 119Sn Mössbauer and XRD measurements on novel Sn-Ni-Fe electrodeposits

被引:0
|
作者
G. B. Lak
E. Kuzmann
M. El-Sharif
C. U. Chisholm
S. Stichleutner
Z. Homonnay
L. Sziráki
机构
[1] Glasgow Caledonian University,Institute of Chemistry
[2] Eötvös Loránd University,Centre for Energy Research, Nuclear Analysis and Radiography Department
[3] Hungarian Academy of Sciences,undefined
来源
Hyperfine Interactions | 2013年 / 218卷
关键词
Sn-Ni-Fe electrodeposit; Pulse plating; Amorphous coating; Fe and ; Sn Mössbauer spectroscopy; X-ray diffractometry; Galvanostatic tests; Batteries;
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中图分类号
学科分类号
摘要
Novel Sn–Ni–Fe ternary alloys were successfully deposited by pulse plating technique from an electrolyte based on sodium gluconate which acts as a complexing agent. XRD results revealed the predominantly amorphous character for the majority of the deposits. 57Fe and 119Sn conversion electron Mössbauer spectroscopy indicated the formation of a paramagnetic amorphous alloy using a short on-pulse duration and where the Fe content was less than 22 wt.%. Galvanostatic charge–discharge tests of the novel Sn-Ni-Fe deposits were carried out in a model Li-ion cell and indicated that the Sn-Ni-Fe alloys have potential as an electrode material.
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页码:145 / 150
页数:5
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