Fe-doped NiCo2O4 hollow hierarchical sphere as an efficient electrocatalyst for oxygen evolution reaction

被引:0
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作者
Wenqing Zheng
Han Sun
Xinping Li
Shu Zhang
Zhuoxun Yin
Wei Chen
Yang Zhou
机构
[1] Qiqihar University,College of Chemistry and Chemical Engineering
[2] Heilongjiang Provincial Key Laboratory of Catalytic Synthesis for Fine Chemicals,College of Science
[3] Qiqihar University,undefined
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关键词
ion exchange; hierarchical nanostructure; electronic structure transfer; oxygen evolution reaction; water splitting;
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摘要
We prepared porous Fe-doped nickel cobaltate (Fe-NiCo2O4) hollow hierarchical nanospheres through a facile self-templated synthetic strategy. Due to the porous hollow structure and composition, the Fe-NiCo2O4 presented vastly superior electrocatalytic activity for the oxygen evolution reaction (OER), compared with NiCo2O4 and the majority of other OER catalysts. With an aim of stimulating a current density of 10 mA·cm−2, the Fe-NiCo2O4 catalyst needs an overpotential of 210 mV, which is on a par with the general properties of commercial IrO2. In addition, the Fe-NiCo2O4 catalyst performed stably in long-term testing. The excellent activity and long-term stability showed that such catalysts have great promise for widespread application in the field of water splitting.
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页码:577 / 588
页数:11
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