Crystal structure of catena(tetraaqua-μ-trans-4-hydroxy-L-proline-O,O′)manganese(II) sulfate

被引：0
|
作者：
Mrozek R. [1 ]
Rza̧czyńska Z. [1 ]
Głowiak T. [2 ]
机构：
[1] Faculty of Chemistry, Maria Curie-Skłodowska Univ.
[2] Institute of Chemistry, University of Wrocław
来源：
Monatshefte für Chemie / Chemical Monthly | 1998年 / 129卷 / 2期
关键词：
Crystal structure; Manganese(II) complexes; trans-4-Hydroxy-L-proline;
D O I：
10.1007/PL00010149
中图分类号：
学科分类号：
摘要：
A new complex of manganese(II) with trans-4-hydroxy-L-proline of the formula [Mn(C5H8NO3) · 4H2O] · SO4 was obtained. The compound was studied by thermal analysis, and the structure was determined by direct X-ray diffraction methods. The compound crystallizes in the triclinic system (space group P1) with a = 7.478(1), b = 9.297(2), c = 9.814(2) Å, α = 87.38(3), β = 67.81(3), γ = 84.21(3)°, Z = 2. The Mn(II) ions are six-fold coordinated being surrounded by two carboxyl oxygen atoms and four water molecules (Mn-O = 2.144(2)-2.255(2) Å). The carboxylate group bridges two adjacent Mn(II) ions and links to a polymeric chain. The sulfate anion is anchored exclusively via hydrogen bonds.
引用
收藏
页码：129 / 137
页数：8
相关论文
共 50 条
  • [1] Crystal structure of catena(tetraaqua-μ-trans-4-hydroxy-L-proline-O,O′)manganese(II) sulfate
    Mrozek, R
    Rzaczynska, Z
    Glowiak, T
    MONATSHEFTE FUR CHEMIE, 1998, 129 (02): : 129 - 137
  • [2] Crystal structure of tetraaqua-(1,10-phenanthroline-N,N′)manganese(II) sulfate dihydrate, [Mn(H2O)4(phen)]SO4 • 2H2O
    Zheng, YQ
    Lin, JL
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2001, 216 (03): : 353 - 354
  • [3] Crystal structure and properties of catena-poly[manganese(II)-mu-dichloro-mu-L-proline-kappa O-2,O'] monohydrate
    Rzaczynska, Z
    Mrozek, R
    Glowiak, T
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 1997, 27 (07) : 417 - 422
  • [4] Crystal structure of catena-poly[tetraaqua-(μ2-succinonitrile-K2N:N′)cobalt(II)] dinitrate, C4H12CoN4O10
    Brito, Ivan
    Gonzalez, Brayan
    Cardenas, Alejandro
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2017, 232 (05): : 837 - 838
  • [5] The crystal structure of trans-tetraaqua-bis(4-acetylphenoxyacetato-κ1O)manganese(II), C20H26O12Mn
    Jie, Yin
    Feng-Jun, Zhang
    Xi-Shi, Tai
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2021, 236 (01): : 45 - 46
  • [6] Crystal structure of tetraaqua-(2-(4-formylphenoxy)acetato-k1O)cadmium(II), C18H22O12Cd
    Tai, Xi-Shi
    Wang, Li-Hua
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2021, 236 (06): : 1379 - 1380
  • [7] Crystal structure of tetraaqua-μ2-pyrazine-zinc(II) squarate, [Zn(H2O)4(C4H4N2)](C4O4)
    Kirchmaier, R
    Altin, E
    Lentz, A
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2004, 219 (01): : 33 - 34
  • [8] Refinement of the crystal structure of the triclinic modification of catena-tetraaquasuccinato-O,O′-manganese(II), Mn(Hn(H2O)4(C4H4O4))
    Zheng, YQ
    Sun, J
    Lin, JL
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2002, 217 (03): : 411 - 412
  • [9] Crystal structure and properties ofcatena-poly[manganese(II)-μ-dichloro-μ-L-proline-k2o,o′] monohydrate
    Z. Rzączyńska
    R. Mrozek
    T. G/klowiak
    Journal of Chemical Crystallography, 1997, 27 (7) : 417 - 422
  • [10] CRYSTAL-STRUCTURE OF CATENA-MU-(N-SALICYLIDENE-L-TYROSINATO-O,O')COPPER(II)
    HAMALAINEN, R
    AHLGREN, M
    TURPEINEN, U
    RANTALA, M
    ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1978, 32 (03): : 235 - 240
12345