The mechanism of the Ni-Fe hydrogenases: a quantum chemical perspective

被引:0
|
作者
Per E. M. Siegbahn
Margareta R.A. Blomberg
Maria Wirstam née Pavlov
Robert H. Crabtree
机构
[1] Department of Physics,
[2] Stockholm University,undefined
[3] Box 6730,undefined
[4] 113 85 Stockholm,undefined
[5] Chemistry Department,undefined
[6] Yale University,undefined
[7] PO Box 208107,undefined
[8] 225 Prospect Street,undefined
[9] New Haven,undefined
[10] CT 06520-8107,undefined
来源
JBIC Journal of Biological Inorganic Chemistry | 2001年 / 6卷
关键词
Ni-Fe hydrogenase Mechanism Theoretical studies Ni-Fe cluster;
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中图分类号
学科分类号
摘要
The catalytic cycle for the heterolytic splitting of H2 by Ni-Fe hydrogenase has been investigated in four recent quantum chemical studies. The mechanisms proposed are described and compared. Although there are clear differences in these mechanisms and in the assignments of the different states observed experimentally, there are also important points of concensus.
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页码:460 / 466
页数:6
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